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在CWPO技术中，非均相催化剂将活性组分负载于载体上，具有活性组分不易流失，催化剂易从水中分离、可循环使用的优势，并大大减少了对反应设备的腐蚀和副反应的发生。大连化物所针对不同性质的工业废水已研发多种高效催化剂，且具备100吨\u002F年的催化剂生产能力。CWPO技术目前已在垃圾渗滤液、煤化工废水及印染废水等多行业废水处理领域中有着重要应用，该技术既可用于废水生化前的预处理，又可用于废水的深度处理。2011年，大连化物所成功完成了CWPO技术处理辽宁宏丰印染废水的中试放大实验，印染废水经CWPO处理后，COD去除率接近80%，色度去除率约90%，处理成本在2.3元\u002F吨。2015年，大连广泰源环保科技有限公司采购大连化物所研发生产的CWPO催化剂60吨，用于处理垃圾渗滤液废水，处理后可达标排放。大连化物所将CWPO技术与广泰源环保科技有限公司的MVR技术进行集成。该组合处理工艺包括预处理系统-蒸发洗气系统-催化湿式过氧化氢氧化系统。蒸发洗气系统处理后出水温度在60-100度之间，出水COD值为80-200 mg\u002FL，催化湿式过氧化氢氧化处理后废水COD值低于50 mg\u002FL。2016年，大连化物所与中钢集团鞍山热能研究院有限公司合作，成功完成了CWPO技术处理煤化工废水的中试研究。2017年，中钢集团鞍山热能研究院有限公司采购大连化物所研发生产的CWPO催化剂100吨，用于煤化工废水处理的工业化放大。该项目进展顺利，近期将开车投入使用。 平台建设单位： 中国科学院科技创新发展局 中国科学院办公厅 国科控股 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闭孔、刚性硬质泡沫。PMI 泡沫呈白色或浅黄色，具有轻质、高强、环保、耐高温、低介电、易加工、耐 疲劳、易粘接、高闭孔率等特点。PMI泡沫与碳纤维，玻璃纤维，铝合金等通过三明治结构组成的新 型复材料，可以简化工艺，缩短周期，解决蜂窝芯材所面临的孔格粗、易吸潮、易脱粘的问题和传统 泡沫芯材强度低、模量低、耐热性差的问题，提升复合材料夹层结构件的寿命可靠性。在航空航天 领域，某些部件泡沫夹层结构已取代蜂窝夹层结构，成为飞行器减重增强的手段之一，PMI泡沫在 适当高温处理后，能承受复合材料固化工艺的高温要求，使得PMI泡沫在航天航空领域得到了广 泛的应用；雷达天线系统中，PMI 泡沫在电气性能上具有良好的电磁波穿透特性，机械性能上也 能经受外部恶劣环境的作用；PMI 泡沫与碳纤维，玻璃纤维，铝合金等通过三明治结构组成的新 型复材，更可应用于无人机，风力发电，汽车制造，轨道交通，船舶游艇等多个领域。 本项目研发了一种独特的 PMI 制备工艺技术，制备的 PMI 泡沫高分子链具有完整的酰亚胺 环结构及链间交联结构，极大地提高了材料的耐热压性能，并且，我们的PMI泡沫具有优异的高温 尺寸和重量稳定性，为复合夹芯材料制备工艺提供了必要的质量保证，克服了PVC、PUR 等芯材在 热压成型过程中可能出现的泡沫崩塌以及面料结合不牢、闭气鼓包等质量问题。目前得到产品经 过检验指标远高于市售高品质产品。","2026-10-09T19:27:30.759Z",3,"合作开发","能源化工及新材料",[493,494,495,498,499,502,503,506,509,510,511,514,515,518,519,520,521,522,525,528,529,530],{"code":399,"name":400},{"code":402,"name":403},{"code":496,"name":497},"GB-30","非金属矿物制品业",{"code":408,"name":409},{"code":500,"name":501},"GB-37","铁路、船舶、航空航天和其他运输设备制造业",{"code":411,"name":412},{"code":504,"name":505},"GB-39","计算机、通信和其他电子设备制造业",{"code":507,"name":508},"GB-44","电力、热力生产和供应业",{"code":414,"name":415},{"code":466,"name":467},{"code":512,"name":513},"GB-74","专业技术服务业",{"code":469,"name":470},{"code":516,"name":517},"SEI-02","高端装备制造产业",{"code":420,"name":421},{"code":432,"name":433},{"code":435,"name":436},{"code":475,"name":476},{"code":523,"name":524},"CH-23","海洋装备",{"code":526,"name":527},"CH-26","电力",{"code":441,"name":442},{"code":444,"name":445},{"code":478,"name":479},[400,403,497,409,501,412,505,508,415,467,513,470,517,421,433,436,476,524,527,442,445,479],{"resultType":386,"id":533,"title":534,"abstract":535,"orgName":451,"province":452,"date":536,"trl":63,"transferMode":490,"keywords":394,"industry":491,"patentType":10,"legalStatus":10,"isOpenLicense":396,"isRevitalized":396,"techMaturity":10,"starRating":10,"licenseFeeText":10,"patentNo":10,"ipc":10,"inventors":10,"tags":537,"tagNames":551},"cmv1bifol08vdbdd8i4igvdib","丙烯双氧水合成环氧丙烷","DMTO等甲醇制烯烃技术已大规模工业化应用；合成气制烯烃已完成中试验证，即将产业化； 丙烷脱氢、轻烃裂解、石油脑裂解等工艺已大规模产业化。上述工业装置产出大量丙烯，除了制造 聚丙烯外，其高值利用受到了工业界和学术界的高度关注。环氧丙烷是丙烯的高值下游产品，也是 丙烯的第二大衍生物，主要用于生产聚醚多元醇、丙二醇和丙二醇醚等，广泛应用于化工、轻工、医 药、食品和纺织等行业。目前我国环氧丙烷产能已达到327万吨\u002F年，且呈逐年递增趋势。预计到 2022 年，将达到500万吨 \u002F年。由中国科学院大连化学物理研究所联合天津大沽化工股份有限公 司开发的液固循环流化床过氧化氢直接氧化丙烯制环氧丙烷新工艺（FHPPO） 已于 2019 年与企 业签订技术开发合同，2021 年签订技术转让合同，已成功完成中试试验，并于2022年初完成中试 现场鉴定。相比现有氯醇法、共氧化法和HPPO工艺，FHPPO工艺强化了反应过程传热传质速率， 有效地抑制了副反应的发生，提高了双氧水有效利用率和产品选择性，极大地简化了工艺生产操 作流程。该新工艺的开发及产业化对提升我国环氧丙烷行业至国际最先进水平，实现环氧丙烷安 全、绿色、清洁生产，保障我国碳三资源产业链的可持续发展具有重要意义。","2026-10-09T19:27:30.236Z",[538,541,544,545,546,547,548,549,550],{"code":539,"name":540},"GB-07","石油和天然气开采业",{"code":542,"name":543},"GB-14","食品制造业",{"code":399,"name":400},{"code":402,"name":403},{"code":466,"name":467},{"code":420,"name":421},{"code":435,"name":436},{"code":444,"name":445},{"code":478,"name":479},[540,543,400,403,467,421,436,445,479],{"resultType":386,"id":553,"title":554,"abstract":555,"orgName":451,"province":452,"date":556,"trl":63,"transferMode":490,"keywords":394,"industry":557,"patentType":10,"legalStatus":10,"isOpenLicense":396,"isRevitalized":396,"techMaturity":10,"starRating":10,"licenseFeeText":10,"patentNo":10,"ipc":10,"inventors":10,"tags":558,"tagNames":571},"cmv1bh3r0061osn4me1b3n6co","丙烯环氧化制环氧丙烷（HPPO）技术","环氧丙烷（PO）是丙烯下游重要的衍生物，其全球产能已超过 1000 万吨。 环氧丙烷广泛应用于化工、轻工、医药、食品和纺织等行业，是一种重要的基本 有机化工原料和化工中间体。近几年来，中国聚氨酯行业蓬勃发展，PO 作为该 行业最重要的基础原料，需求量不断增加，市场前景广阔。丙烯直接环氧化法 （HPPO法）是以TS-1分子筛为催化剂，以双氧水和丙烯为原料直接氧化制备环 氧丙烷的新工艺，该过程工艺流程简单，产品收率高，具有无可比拟的环保和经 济优势，也是目前国内唯一允许产品出口的生产工艺。目前，国内的 HPPO 工业 化装置均没有正常运行，其核心原因是催化剂的活性和稳定性仍需进一步提高。 本课题组开发了TS-1合成新方法，合成的TS-1分子筛具有高含量的骨架钛物种 和纳米尺度的粒径，在丙烯环氧化反应中双氧水的转化率和有效利用率均得到明 显提升；开发了 TS-1 分子筛成型技术，保持了分子筛原粉的高活性同时提高了 产品中 PO 的选择性。与目前国内外现有技术相比，双氧水的转化率、丙烯单耗、 甲醇用量都有不同程度的降低，解决了目前HPPO技术中存在的流出物中PO浓度 较低、甲醇循环量大、能耗高以及副产物含量高的关键问题。已完成丙烯直接环 氧化制被环氧丙烷（HPPO）技术开发，可与企业合作共同进行10万吨\u002F年及以上 规模工业示范。  合作方式 合作开发  投资规模 大于1亿 辽宁省大连市中山路457号 116023 Tel: 0411-84379025 http:\u002F\u002Fwww.dicp.ac.cn Ni@SiO 纳米反应器催化甲烷干重整制合成气","2026-10-09T19:27:30.134Z","能源化工",[559,560,561,562,565,566,569,570],{"code":542,"name":543},{"code":399,"name":400},{"code":402,"name":403},{"code":563,"name":564},"GB-27","医药制造业",{"code":469,"name":470},{"code":567,"name":568},"CH-10","生物医药",{"code":475,"name":476},{"code":478,"name":479},[543,400,403,564,470,568,476,479],{"resultType":386,"id":573,"title":574,"abstract":575,"orgName":451,"province":452,"date":576,"trl":32,"transferMode":577,"keywords":394,"industry":578,"patentType":10,"legalStatus":10,"isOpenLicense":396,"isRevitalized":396,"techMaturity":10,"starRating":10,"licenseFeeText":10,"patentNo":10,"ipc":10,"inventors":10,"tags":579,"tagNames":590},"cmv1bifg808r9bdd8pwnufoh1","低短链氯化石蜡含量的中长链氯化石蜡工业生产技术","利用氯气与石蜡反应得到的氯化石蜡产品广泛应用于PVC增塑剂、阻燃剂、皮革、纺织和金 属切削液等行业。同时，氯化石蜡也是我国氯碱化工企业平衡氯气的重要产品。按所使用石蜡原料 中正构烷烃碳链长度可将氯化石蜡分为三类：短链氯化石蜡、中链氯化石蜡和长链氯化石蜡。近 年来，研究不断发现短链氯化石蜡对环境有负面影响。联合国环保署已召开审查会议将短链氯化 石蜡列入了《关于持久性有机污染物的斯德哥尔摩公约》禁止使用的持久性有机污染物清单之中。 短链氯化石蜡以及含短链氯化石蜡超标(>1%)的氯化石蜡产品将很快被禁止生产、销售和使用。 本项目利用催化热氯化技术使氯气与石蜡在较温和的条件下反应得到短链氯化石蜡含量 \u003C1%的氯化石蜡产品。最优工艺比传统热\u002F光氯化工艺效率提高30%，由此得到短链氯化石蜡含 量为0.1%的氯化石蜡-52 产品，质量符合欧美产品标准。煤( 合成气)制油副产的重蜡也可以用 3 作低短链氯化石蜡含量的中长链氯化石蜡生产的原料。技术经过 6 m 反应釜规模工艺试用。获得 中国发明专利1件(余正坤等，一种多氯烷烃的合成方法，专利号ZL 201110282332.X，授权时间 2014-11-19)。 Cl2 C14-18液蜡 + C19-30固蜡 中长硅氯化石蜡 催化剂 Cl2","2026-10-09T19:27:29.932Z","技术许可","精细化工",[580,581,584,585,586,587,588,589],{"code":399,"name":400},{"code":582,"name":583},"GB-19","皮革、毛皮、羽毛及其制品和制鞋业",{"code":402,"name":403},{"code":466,"name":467},{"code":512,"name":513},{"code":469,"name":470},{"code":475,"name":476},{"code":478,"name":479},[400,583,403,467,513,470,476,479],{"resultType":386,"id":592,"title":593,"abstract":594,"orgName":451,"province":452,"date":595,"trl":489,"transferMode":596,"keywords":394,"industry":578,"patentType":10,"legalStatus":10,"isOpenLicense":396,"isRevitalized":396,"techMaturity":10,"starRating":10,"licenseFeeText":10,"patentNo":10,"ipc":10,"inventors":10,"tags":597,"tagNames":610},"cmv1bifd908pybdd8ogzi8fia","制备工艺研究","我国石油化工催化裂解装置副产大量 C4 资源，主要成分为丁二烯、叔丁醇、异丁烯等。经 过分离丁二烯等其他成分后，可得到大量叔丁醇、异丁烯，而且在催化剂作用下叔丁醇可脱水 得到异丁烯，因此以异丁烯为原料制备其高附加值下游产品甲基丙烯腈和甲基丙烯酸甲酯是充 分利用C4的有效途径。目前，工业上以异丁烯为原料直接制备甲基丙烯腈是高温气相反应工艺。 甲基丙烯酸甲酯的制备工艺主要是三步法，并且国外垄断现有的主要工艺技术。由异丁烯催化 氧化得到甲基丙烯醛，再由甲基丙烯醛直接氧化氨化（或酯化）为甲基丙烯腈（或者甲基丙烯 酸甲酯）；该工艺路线简化了甲基丙烯醛氧化过程及分离中间产物的设备，原子经济性高，可实 现甲基丙烯腈和甲基丙烯酸甲酯的绿色化生产。目前，异丁烯制备甲基丙烯醛技术已经成熟， 本项目为甲基丙烯醛一步液相催化氧化氨化（或者酯化）为甲基丙烯腈（或者甲基丙烯酸甲酯）。 甲基丙烯腈：甲基丙烯腈是一种重要的有机合成原料，尤其是制备聚甲基丙烯酰亚胺（PMI）的 原料⸺重要的芯层材料，用于航空航天、车辆、船舶等高科技领域。研发了一种含锰催化剂材 料用于制造塑料、涂料、粘合剂、PVC 改性剂、高档轿车漆、纺织浆料、高级酯类油品添加剂 等精细化学品。研发由一种甲基丙烯醛分钟氧选择氧化同时和甲醇发生酯化反应生成甲基丙烯 酸甲酯的新型纳米金催化剂材料，与已有工业化催化材料相比，本项目催化材料制备过程简单， 催化剂成分简单，反应条件温和，催化剂效率高等特点。","2026-10-09T19:27:29.820Z","技术转让",[598,599,600,601,602,603,604,605,606,607,608,609],{"code":539,"name":540},{"code":399,"name":400},{"code":402,"name":403},{"code":405,"name":406},{"code":500,"name":501},{"code":414,"name":415},{"code":466,"name":467},{"code":432,"name":433},{"code":523,"name":524},{"code":441,"name":442},{"code":444,"name":445},{"code":478,"name":479},[540,400,403,406,501,415,467,433,524,442,445,479],{"resultType":386,"id":612,"title":613,"abstract":614,"orgName":451,"province":452,"date":615,"trl":63,"transferMode":577,"keywords":394,"industry":578,"patentType":10,"legalStatus":10,"isOpenLicense":396,"isRevitalized":396,"techMaturity":10,"starRating":10,"licenseFeeText":10,"patentNo":10,"ipc":10,"inventors":10,"tags":616,"tagNames":636},"cmv1bifa508o6bdd83gk88oph","500 万 ~1000 万","甲基丙烯酸甲酯（MMA）是一种重要的有机化工原料，主要用来生产有机玻璃（聚甲基丙烯酸 甲酯，PMMA），也用来制造其它树脂、塑料、涂料、粘合剂、润滑剂、木材和软木的浸润剂、电机线圈 的浸透剂、纸张上光剂、印染助剂和绝缘灌注材料等，用途十分广泛。近年来，亚洲市场对电子\u002F电 器\u002F光学用品、显示标志、各种照明设备和灯具需求旺盛，推动了MMA行业的快速发展。此外，在 玩具、文具及其他物品对透明树脂需求继续大增的同时，LCD核心元件背光用光板和广告宣传标 志牌等用途的需求量也有很大发展。 目前，丙酮氰醇法和异丁烯法（甲基丙烯酸-甲醇酯化法）是MMA主流工艺，技术成熟可靠， 各有优缺点。丙酮氰醇工艺简单，产品质量较好，经济性较好。但是，受到原料氢氰酸来源和环保等 多方面因素限制；氢氰酸和硫酸腐蚀性很强，对设备耐腐蚀性要求很高。异丁烯法（甲基丙烯酸- 甲醇酯化法）原料易得、产品质量好，对环境影响较小。但是，甲基丙烯酸腐蚀性较强，对设备耐腐 蚀性要求较高；工艺流程较长，能耗较高。最新的异丁烯法（甲基丙烯醛- 甲醇一步氧化酯化法）可 以有效缩短工艺流程，大幅度增强异丁烯法的竞争力。甲基丙烯醛来源除了异丁烯氧化外，也可以 通过乙烯甲酰化合成丙醛，丙醛再和甲醛缩合而制得。目前，甲基丙烯醛和甲醇一步氧化酯化新工 艺被日本旭化成垄断，如果能成功开发此新工艺，将对打破国外技术垄断和提升我国MMA 行业水 平起到极大推动作用。同时，可满足我国快速增长的MMA市场需求。 本项目聚焦于纳米金催化剂高效制备及催化甲基丙烯醛和甲醇一步氧化酯化制甲基丙烯酸 甲酯，空气或氧气作为氧化剂。已完成催化剂 3800 小时长寿命考察，纳米金催化剂性能优异。甲 基丙烯醛几乎完全转化，MMA 选择性可达到 98% 以上。已于 2016 年与企业签订技术开发合同， 2019年签订催化剂技术转让合同，2020年完成了项目中试，20","2026-10-09T19:27:29.697Z",[617,618,621,624,625,626,627,628,629,630,633,634,635],{"code":399,"name":400},{"code":619,"name":620},"GB-20","木材加工和木、竹、藤、棕、草制品业",{"code":622,"name":623},"GB-24","文教、工美、体育和娱乐用品制造业",{"code":402,"name":403},{"code":405,"name":406},{"code":496,"name":497},{"code":411,"name":412},{"code":463,"name":464},{"code":469,"name":470},{"code":631,"name":632},"CH-12","新型显示",{"code":475,"name":476},{"code":444,"name":445},{"code":478,"name":479},[400,620,623,403,406,497,412,464,470,632,476,445,479],{"resultType":386,"id":638,"title":639,"abstract":640,"orgName":451,"province":452,"date":641,"trl":32,"transferMode":490,"keywords":394,"industry":578,"patentType":10,"legalStatus":10,"isOpenLicense":396,"isRevitalized":396,"techMaturity":10,"starRating":10,"licenseFeeText":10,"patentNo":10,"ipc":10,"inventors":10,"tags":642,"tagNames":656},"cmv1bieth08g9bdd8w1dudirx","甲基丙烯腈绿色清洁制备工艺研究","甲基丙烯腈是一种重要的有机合成原料，尤其是制备聚甲基丙烯酰亚胺（PMI）的原料⸺重 要的芯层材料，用于航空航天、车辆、船舶等高科技领域。还可用于制造塑料、涂料、粘合剂、PVC改 性剂、高档轿车漆、纺织浆料、高级酯类油品添加剂等精细化学品。目前，工业生产技术被国外垄 断，主要是以异丁烯为原料直接制备甲基丙烯腈是高温气相反应工艺，该步骤存在异丁烯成本高， 能耗大，流程复杂，选择性差（副产氢氰酸、乙腈、丙烯腈、二氧化碳和聚合物等），污染大，对催化剂 的设计和制备要求高等问题。本项目开发了甲醛和丙醛为原料，经Mannich缩合法得到甲基丙烯 醛，再由甲基丙烯醛一步液相催化氨氧化制备甲基丙烯腈的两步工艺技术。第一步甲醛和丙醛缩 合法制备甲基丙烯醛工艺，具有反应条件温和、操作简单、副产物少等优点，具有良好的工业应用 前景。第二步工艺开发的甲基丙烯醛催化氨氧化制备甲基丙烯腈的新型廉价金属催化剂材料，具 有制备简单，反应条件温和（\u003C100 ℃）、催化剂效率高、循环稳定性好等特点。 本项目研发的液相 制备甲基丙烯腈工艺路线，以甲醛和丙醛为原料，具有反应条件温和，后处理简单，原子经济性高， 绿色环保等优点，可实现甲基丙烯腈的绿色化生产。该工艺路线中试放大生产的产品纯度高，色度 低，适合于下游产品PMI 的制备，具有很强的经济效益和市场竞争力。","2026-10-09T19:27:29.052Z",[643,644,645,646,647,648,649,650,651,652,653,654,655],{"code":399,"name":400},{"code":402,"name":403},{"code":405,"name":406},{"code":500,"name":501},{"code":414,"name":415},{"code":466,"name":467},{"code":469,"name":470},{"code":432,"name":433},{"code":475,"name":476},{"code":523,"name":524},{"code":441,"name":442},{"code":444,"name":445},{"code":478,"name":479},[400,403,406,501,415,467,470,433,476,524,442,445,479],{"resultType":386,"id":658,"title":659,"abstract":660,"orgName":451,"province":452,"date":661,"trl":63,"transferMode":662,"keywords":394,"industry":663,"patentType":10,"legalStatus":10,"isOpenLicense":396,"isRevitalized":396,"techMaturity":10,"starRating":10,"licenseFeeText":10,"patentNo":10,"ipc":10,"inventors":10,"tags":664,"tagNames":687},"cmv1bh1sj05f0sn4mu5brbiu6","VOCs催化脱除技术","项目简介及应用领域 挥发性有机气体（VOCs）是导致大气雾霾的重要诱因，VOCs 的排放涉及化工、喷涂、印刷、制药、塑料和橡胶加工等众多行业，其成分复杂，大体包括 三苯类（芳香烃、多环芳香烃等）、含氧类 VOCs（醇类、酮类、酚类、醛类和酯类等）、烃类（如烷烃、烯烃）、含杂原子 VOCs（如卤代烃等）以及低碳烷烃类（如乙烷、丙烷等）。鉴于 VOCs 对环境和对人体健康的危害，其排放控制引起了各国政府的高度重视。美国、欧盟、日本等相继出台了一系列 VOCs 排放标准及减排计划。我国在十三五规划纲要中，明确提出将 VOCs 排放纳入总量控制范畴。VOCs 的排放控制技术主要可分为物理回收和化学降解两大类技术，而化学降解法中的催化氧化技术，具有适用处理废气浓度范围广、能彻底将 VOCs 转化为 CO2 和 H2O，无二次污染问题，并且可处理易燃易爆气体，是 VOCs 净化 的最有效方法。大连化物所在科技部重点研发项目、自然科学基金项目、中科院STS 项目等资助下，针对典型的四类 VOCs 气源特点，进行了 VOCs 氧化催化剂 及工艺技术的开发。开发出针对含氧类 VOCs、芳香类、低碳烷烃类以及含杂原子类等系列 VOCs 净化催化剂。开发的广谱性燃烧催化剂，已成功应用于涂装、印染、石化等 5 个工业项目。开发的耐卤素燃烧催化剂也已应用于对苯二甲酸尾气催化净化工业项目中。此外，开发的丙烯酸尾气、丙烯腈尾气净化催化剂已完成工业侧线试验， 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